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Methyl cellulose

CAS No.: 9004-67-5
Formula: C20H38O11
Molecular Weight: 454.50912
Suppliers: All(0) China Suppliers(0) Products(19)
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  • Basic Info
  • Safety Info
  • MSDS
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What is Methyl cellulose

**Introduction to Methyl Cellulose** Methyl cellulose is a versatile, water-soluble polymer derived from cellulose, widely used in industries such as food, pharmaceuticals, cosmetics, and construction. As a non-toxic, biodegradable compound, it acts as a thickener, emulsifier, binder, and film-forming agent. In food, it serves as a vegetarian alternative to gelatin, improving texture in products like sauces and ice cream. In pharmaceuticals, it enhances drug delivery systems and acts as a lubricant in eye drops. Its water-retention properties make it valuable in construction materials like tile adhesives and cement. Methyl cellulose is prized for its thermal gelation, forming gels upon heating, and its compatibility with other ingredients, ensuring broad applicability.

Preparation Process: Methyl cellulose is prepared by treating cellulose with an alkaline solution, typically sodium hydroxide, to form alkali cellulose. The alkali cellulose is then reacted with methyl chloride in a pressurized reactor at elevated temperatures (50–100°C) to introduce methyl groups (-CH₃) onto the hydroxyl groups of the cellulose backbone. The degree of substitution (DS) is controlled by adjusting the molar ratio of methyl chloride to cellulose. After the reaction, the product is neutralized, washed with hot water to remove byproducts (e.g., salts and unreacted reagents), and dried. The resulting methyl cellulose is a white or off-white powder, soluble in cold water but insoluble in hot water.

Usage Scenarios: Methyl cellulose is a water-soluble polymer derived from cellulose, widely used as a thickener, stabilizer, and emulsifier in food, pharmaceuticals, and cosmetics. In food, it improves texture in products like ice cream and sauces. In pharmaceuticals, it acts as a binder in tablets and a lubricant in eye drops. It also serves as a non-toxic adhesive in construction materials like wallpaper paste. In personal care products, it enhances viscosity in shampoos and lotions. Additionally, methyl cellulose is employed as a temporary support material in 3D printing and as a vegetarian alternative to gelatin in vegan foods. Its water-retention properties make it useful in agriculture and ceramics.

Methyl cellulose Basic Info
Chemical Name Methyl cellulose
Synonyms MC;methocel;MODIFIED CELLULOSE;tylose;Methyl ether cellulose;Methylcellulose, 400 cP, FCC;Methyl cellulose - Viscosity 40000 cPs;nicel;viscol;adulsin
CAS No. 9004-67-5
Molecular Formula C20H38O11
Molecular Weight 454.50912
PSA 147.68000
LogP -0.37790
Safely Info
RTECS FJ5959000
Hazard Class -
Safety Statements 24/25
HS Code 39129000
WGK Germany -
Packing Group -
RIDADR -
Risk Statements -
Hazard Codes -
Caution Statement -
Hazard Declaration -
Symbol -
Signal Word -
Methyl cellulose Price
United States: $10 - $50
China: $5 - $30
Russia: $15 - $60
Germany: $20 - $70
India: $8 - $40
Japan: $25 - $80
Brazil: $10 - $50
South Korea: $10 - $45
Philippines: $5 - $35
United Kingdom: $15 - $55
France: $20 - $60
Mexico: $10 - $45
Canada: $15 - $50
South Africa: $8- $40
Egypt: $10 - $50
Turkey: $12 - $50
Thailand: $8 - $45
Indonesia: $5 - $35
MSDS
MSDS
Name: Methyl cellulose (viscosity: ca 15 cP(2% solution in water)) Material Safety Data Sheet
Synonym: Cellulose, methyl ether; Adulsin; Bagolax; Bufapto methalose; Bulkaloid; Mellose; Methocel 10; Methyl cellulose ether; Tylose M
CAS: 9004-67-5
Section 1 - Chemical Product   MSDS Name:Methyl cellulose (viscosity: ca 15 cP(2% solution in water)) Material Safety Data Sheet
Synonym:Cellulose, methyl ether; Adulsin; Bagolax; Bufapto methalose; Bulkaloid; Mellose; Methocel 10; Methyl cellulose ether; Tylose M

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
9004-67-5 Methyl cellulose app.100 232-674-9
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Ingestion of large quantities will produce a laxative effect and may be irritating to the digestive tract. Esophageal, gastric, small intestinal and rectal obstruction may occur due to osmotic disturbance.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Dusts at sufficient concentrations can form explosive mixtures with air. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 9004-67-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Powder
Color: white granular
Odor: odorless
pH: Neutral to Litmus
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Soluble in cold water.
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Calcium oxide, bleeching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrite, sodium nitrate, strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 9004-67-5: FJ5959000 LD50/LC50:
Not available.
Carcinogenicity:
Methyl cellulose - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
  Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 9004-67-5: 1
Canada
CAS# 9004-67-5 is listed on Canada's DSL List.
CAS# 9004-67-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 9004-67-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
SDS 1.0
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