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ABS Resins

CAS No.: 9003-56-9
Formula: C45H51N3X2
Molecular Weight: 633.91
Suppliers: All(0) China Suppliers(1) Products(21)
  • Description
  • Basic Info
  • Safety Info
  • MSDS
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What is ABS Resins

**Introduction to ABS Resins** ABS (Acrylonitrile Butadiene Styrene) resin is a versatile thermoplastic polymer known for its excellent impact resistance, strength, and machinability. Combining the rigidity of acrylonitrile, the toughness of butadiene, and the processability of styrene, ABS offers a balanced performance for various industrial and consumer applications. It is lightweight, durable, and resistant to chemicals, making it ideal for automotive parts, electronic housings, toys (such as LEGO bricks), and household appliances. ABS can be easily molded, extruded, or 3D printed, and it accepts coatings and adhesives well. With its affordability and adaptability, ABS remains a preferred choice for manufacturers seeking a reliable, high-performance engineering plastic.

Preparation Process: ABS (Acrylonitrile-Butadiene-Styrene) resins are prepared through emulsion, suspension, or bulk polymerization. The most common method involves grafting acrylonitrile and styrene onto a polybutadiene rubber backbone. 1. **Emulsion Polymerization**: A pre-formed polybutadiene latex is mixed with acrylonitrile and styrene monomers. Initiators (e.g., peroxides) and emulsifiers are added to facilitate grafting. The reaction occurs at 50–70°C, forming a graft copolymer. 2. **Suspension Polymerization**: Monomers are dispersed in water with stabilizers, then polymerized under agitation. 3. **Bulk Polymerization**: A continuous process where monomers are polymerized in the absence of solvents. The resulting ABS resin is then coagulated, washed, dried, and pelletized for commercial use.

Usage Scenarios: ABS resins (Acrylonitrile Butadiene Styrene) are widely used in various industries due to their durability, impact resistance, and thermal stability. Common applications include automotive parts (dashboards, wheel covers), consumer electronics (keyboards, housings), and toys (LEGO bricks). They are also used in piping systems, medical devices, and protective gear due to chemical resistance. ABS resins are easily molded, machined, and 3D printed, making them ideal for prototyping and manufacturing. Their ability to be electroplated or painted enhances aesthetic appeal in appliances and decorative items. Additionally, ABS is used in luggage, sporting goods, and construction materials for its lightweight yet robust properties.

ABS Resins Basic Info
Chemical Name ABS Resins
Synonyms abs;Acrylonitrile-butadiene-styrene;ACRYLONITRILE-BUTADIENE-STYRENE RESIN;acrylonitrile-butadiene-styrenecopolymers;ACRYLONITRILE-BUTADIENE-STYRENE COPOLYMER;KRYLENE;ABS rod;absresin;absresins;ABSPOLYMER
CAS No. 9003-56-9
Molecular Formula C45H51N3X2
Molecular Weight 633.91
PSA 23.79000
LogP 4.38398
Safely Info
RTECS AT6970000
Hazard Class -
Safety Statements 26-36
HS Code -
WGK Germany -
Packing Group -
RIDADR -
Risk Statements 22-36/37/38-20/21/22
Hazard Codes Xn
Caution Statement P264-P280-P305+P351+P338-P337+P313P-P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362
Hazard Declaration H302-H335-H315-H319
Symbol GHS07
Signal Word Warning
ABS Resins Price
Here is a rough price range for ABS Resins in the listed countries. Note that prices can vary based on quality, quantity, and market conditions:

1. **United States**: $1.50 - $2.50 per kg
2. **China**: $1.20 - $2.00 per kg
3. **Russia**: $1.50 - $2.30 per kg
4. **Germany**: $1.70 - $2.60 per kg
5. **India**: $1.30 - $2.10 per kg
6. **Japan**: $1.80 - $2.70 per kg
7. **Brazil**: $1.60 - $2.40 per kg
8. **South Korea**: $1.50 - $2.30 per kg
9. **Philippines**: $1.40 - $2.20 per kg
10. **United Kingdom**: $1.70 - $2.60 per kg
11. **France**: $1.70 - $2.60 per kg
12. **Mexico**: $1.50 - $2.30 per kg
13. **Canada**: $1.60 - $2.50 per kg
14. **South Africa**: $1.50 - $2.20 per kg
15. **Egypt**: $1.40 - $2.10 per kg
16. **Turkey**: $1.50 - $2.30 per kg
17. **Thailand**: $1.30 - $2.00 per kg
18. **Indonesia**: $1.30 - $2.00 per kg

If no specific data is available for a country, it is marked as "No results." Prices are approximate and subject to change based on market conditions.
MSDS
MSDS
Name: Poly(acrylonitrile-co-butadiene-co-styrene) Material Safety Data Sheet
Synonym: 2-Propenitrile, polymer with 1,3-butadiene and ethenylbenzene
CAS: 9003-56-9
Section 1 - Chemical Product   MSDS Name:Poly(acrylonitrile-co-butadiene-co-styrene) Material Safety Data Sheet
Synonym:2-Propenitrile, polymer with 1,3-butadiene and ethenylbenzene

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
9003-56-9 Poly(acrylonitrile-butadiene-styrene) 100 unlisted
Hazard Symbols: T
Risk Phrases: 20/21/22 45

Section 3 - HAZARDS IDENTIFICATION
  EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. May cause cancer.
Potential Health Effects
Eye:
May cause eye irritation. The toxicological properties of this material have not been fully investigated.
Skin:
May cause skin irritation. The toxicological properties of this material have not been fully investigated.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
  Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid immediately. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
  General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
  General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Forms smooth, slippery surfaces on floors, posing an accident risk.
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.

Section 7 - HANDLING and STORAGE
  Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
  Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 9003-56-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
 
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C15H17N1x
Molecular Weight: 197.119

Section 10 - STABILITY AND REACTIVITY
  Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
  RTECS#:
CAS# 9003-56-9: AT6970000 LD50/LC50:
Not available.
Carcinogenicity:
Poly(acrylonitrile-butadiene-styrene) - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
 

Section 13 - DISPOSAL CONSIDERATIONS
  Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
 
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
 
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 45 May cause cancer.
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 9003-56-9: No information available.
Canada
CAS# 9003-56-9 is listed on Canada's DSL List.
CAS# 9003-56-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 9003-56-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A
SDS 1.0
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