Geranyl linalool C20H34O Properties,Formula,Price, Uses

What is Geranyl linalool

**Introduction to Geranyl Linalool** Geranyl linalool is a naturally occurring acyclic sesquiterpene alcohol, widely recognized for its pleasant floral and woody aroma. Found in various plants, including lavender, tea tree, and cannabis, it serves as a key fragrance ingredient in perfumes, cosmetics, and aromatherapy products. Beyond its olfactory appeal, geranyl linalool exhibits potential therapeutic properties, such as anti-inflammatory and antioxidant effects, making it valuable in skincare and wellness formulations. It also acts as a precursor in the biosynthesis of other terpenes and pheromones in nature. With its versatile applications and mild, soothing scent, geranyl linalool is a sought-after compound in the fragrance, cosmetic, and pharmaceutical industries.

Preparation Process: Geranyl linalool can be synthesized via the condensation of geraniol and linalool in the presence of an acid catalyst, such as p-toluenesulfonic acid (PTSA). Alternatively, it can be prepared through the allylation of linalool with geranyl bromide under basic conditions (e.g., NaH or KOH). Another method involves the enzymatic esterification of geraniol and linalool using lipases in a non-aqueous solvent. The reaction mixture is typically purified by column chromatography or distillation to isolate the product. Careful control of temperature (20–60°C) and reaction time (4–12 hours) ensures optimal yield. Solvents like toluene or THF are commonly used.

Usage Scenarios: Geranyl linalool is a naturally occurring terpene alcohol used primarily in the fragrance and flavor industries for its floral, citrusy, and woody aroma. It serves as a key ingredient in perfumes, cosmetics, and personal care products, enhancing scent profiles. In aromatherapy, it contributes to relaxation and stress relief. Additionally, it acts as a pheromone or attractant in pest control. Geranyl linalool is also studied for potential antimicrobial and anti-inflammatory properties. Its stability and pleasant scent make it valuable in household cleaners and air fresheners. In some cases, it is used as a precursor in the synthesis of other fragrance compounds.

Geranyl linalool Basic Info

Chemical Name Geranyl linalool

Synonyms 1,6,10,14-Hexadecatetraen-3-ol, 3,7,11,15-tetramethyl-, (E,E)-;GERANYL LINALOL;(6E,10E)-3,7,11,15-Tetramethylhexadeca-1,6,10,14-tetraen-3-ol;GERANYL LINALOOL;Xiangye Linalool;T-Geranyl Linalool;(E)-geranyl linalool;(E,E)-GERANYL LINALOOL;Menatetrenone ImpuritiesD;Geranyl linalool, tech., ca. 95%

CAS No. 1113-21-9

Molecular Formula C20H34O

Molecular Weight 290.48

PSA 20.23000

LogP 6.12280

Safely Info

RTECS MM0335000

Hazard Class -

Safety Statements 26-36

HS Code 29052200

WGK Germany 2

Packing Group -

RIDADR -

Risk Statements 36/37/38

Hazard Codes Xi

Caution Statement P261-P264-P271-P280-P302+P352-P305+P351+P338

Hazard Declaration H315-H319-H335

Symbol GHS07

Signal Word Warning

Geranyl linalool Price

United States: $50-$100
China: $30-$60
Russia: $40-$80
Germany: $60-$120
India: $20-$40
Japan: $70-$140
Brazil: $35-$70
South Korea: $45-$90
Philippines: $25-$50
United Kingdom: $55-$110
France: $65-$130
Mexico: $30-$60
Canada: $50-$100
South Africa: No results
Egypt: $40-$80
Turkey: $35-$70
Thailand: $25-$50
Indonesia: $20-$40

MSDS

Name:	Geranyl linalool, tech.,ca.95%, mixture of isomers Material Safety Data Sheet
Synonym:	3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraene-3-ol; E,E-3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraen-3-ol
CAS:	1113-21-9

Section 1 - Chemical Product MSDS Name: Geranyl linalool, tech.,ca.95%, mixture of isomers Material Safety Data Sheet
Synonym: 3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraene-3-ol; E,E-3,7,11,15-Tetramethyl-1,6,10,14-hexadecatetraen-3-ol

SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
1113-21-9	Geranyl linalool, tech., mixture of is	ca. 95	214-201-8

Hazard Symbols: XI
Risk Phrases: 38

SECTION 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Irritating to skin. Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Chronic:
Effects may be delayed.

SECTION 4 - FIRST AID MEASURES
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

SECTION 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

SECTION 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Cover with sand, dry lime or soda ash and place in a closed container for disposal. Provide ventilation.

SECTION 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 1113-21-9: Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Clear liquid
Color: clear slightly yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: <1 mbar @ 20 C
Viscosity: Not available.
Boiling Point: 250 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Flash Point: 160 deg C ( 320.00 deg F)
Explosion Limits, lower: .50 vol %
Explosion Limits, upper: 2.10 vol %
Decomposition Temperature: Not available.
Solubility in water: insoluble
Specific Gravity/Density: .8830g/cm3
Molecular Formula: C20H34O
Molecular Weight: 290.48

SECTION 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat, strong oxidants, very acidic or very alkaline substances.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, acrid smoke and fumes.
Hazardous Polymerization: Will not occur.

SECTION 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 1113-21-9: MM0335000
LD50/LC50:
CAS# 1113-21-9: Draize test, rabbit, eye: 100 mg; Draize test,
rabbit, skin: 500 mg; Oral, rat: LD50 = >5 gm/kg; Skin, rabbit: LD50 = >5 gm/kg.
Carcinogenicity:
Geranyl linalool, tech., mixture of isomers - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

SECTION 12 - ECOLOGICAL INFORMATION Other No information available.

SECTION 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations.

SECTION 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Not regulated as a hazardous material.

SECTION 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 38 Irritating to skin.
Safety Phrases:
WGK (Water Danger/Protection) CAS# 1113-21-9: No information available. Canada CAS# 1113-21-9 is listed on Canada's DSL List. CAS# 1113-21-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 1113-21-9 is listed on the TSCA inventory.

SECTION 16 - ADDITIONAL INFORMATION
MSDS Creation Date: 9/02/1997 Revision #4 Date: 3/18/2003 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages.

SECTION 16 - ADDITIONAL INFORMATION
N/A

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1.Identification

1.1 GHS Product identifier

Product name	Geranyl linalool

1.2 Other means of identification

Product number	-
Other names	3,7,11,15-Tetramethyl-1,6E,10E,14-hexadecatetraen-3-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only. Food additives -> Flavoring Agents
Uses advised against	no data available

1.4 Supplier's details

Company	MOLBASE (Shanghai) Biotechnology Co., Ltd.
Address	Floor 4 & 5, Building 12, No. 1001 North Qinzhou Road, Xuhui District, Shanghai, China
Telephone	+86(21)64956998
Fax	+86(21)54365166

1.5 Emergency phone number

Emergency phone number	+86-400-6021-666
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

2.Hazard identification

2.1 Classification of the substance or mixture

Skin irritation, Category 2

2.2 GHS label elements, including precautionary statements

Pictogram(s)
Signal word	Warning
Hazard statement(s)	H315 Causes skin irritation
Precautionary statement(s)
Prevention	P264 Wash ... thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection.
Response	P302+P352 IF ON SKIN: Wash with plenty of water/... P321 Specific treatment (see ... on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse.
Storage	none
Disposal	none

2.3 Other hazards which do not result in classification

none

3.Composition/information on ingredients

3.1 Substances

Chemical name	Common names and synonyms	CAS number	EC number	Concentration
Geranyl linalool	Geranyl linalool	1113-21-9	none	100%

4.First-aid measures

4.1 Description of necessary first-aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

In case of skin contact

Wash off with soap and plenty of water. Consult a physician.

In case of eye contact

Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

4.2 Most important symptoms/effects, acute and delayed

no data available

4.3 Indication of immediate medical attention and special treatment needed, if necessary

no data available

5.Fire-fighting measures

5.1 Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

5.2 Specific hazards arising from the chemical

no data available

5.3 Special protective actions for fire-fighters

Wear self-contained breathing apparatus for firefighting if necessary.

6.Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8.

6.2 Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

6.3 Methods and materials for containment and cleaning up

Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

7.Handling and storage

7.1 Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

8.Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure limit values

no data available

Biological limit values

no data available

8.2 Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

8.3 Individual protection measures, such as personal protective equipment (PPE)

Eye/face protection

Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

Respiratory protection

Wear dust mask when handling large quantities.

Thermal hazards

no data available

9.Physical and chemical properties

Physical state	clear colourless to pale yellowish liquid
Colour	no data available
Odour	no data available
Melting point/ freezing point	51ºC
Boiling point or initial boiling point and boiling range	250ºC
Flammability	no data available
Lower and upper explosion limit / flammability limit	no data available
Flash point	160ºC
Auto-ignition temperature	no data available
Decomposition temperature	no data available
pH	no data available
Kinematic viscosity	no data available
Solubility	In water:insoluble
Partition coefficient n-octanol/water (log value)	no data available
Vapour pressure	1.09E-07mmHg at 25°C
Density and/or relative density	0.885
Relative vapour density	no data available
Particle characteristics	no data available

10.Stability and reactivity

10.1 Reactivity

no data available

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

no data available

10.4 Conditions to avoid

no data available

10.5 Incompatible materials

no data available

10.6 Hazardous decomposition products

no data available

11.Toxicological information

Acute toxicity

Oral: no data available
Inhalation: no data available
Dermal: no data available

Skin corrosion/irritation

no data available

Serious eye damage/irritation

no data available

Respiratory or skin sensitization

no data available

Germ cell mutagenicity

no data available

Carcinogenicity

no data available

Reproductive toxicity

no data available

STOT-single exposure

no data available

STOT-repeated exposure

no data available

Aspiration hazard

no data available

12.Ecological information

12.1 Toxicity

Toxicity to fish: no data available
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to microorganisms: no data available

12.2 Persistence and degradability

no data available

12.3 Bioaccumulative potential

no data available

12.4 Mobility in soil

no data available

12.5 Other adverse effects

no data available

13.Disposal considerations

13.1 Disposal methods

Product

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Contaminated packaging

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

14.Transport information

14.1 UN Number

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.2 UN Proper Shipping Name

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.3 Transport hazard class(es)

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.4 Packing group, if applicable

ADR/RID: no data available

IMDG: no data available

IATA: no data available

14.5 Environmental hazards

ADR/RID: no

IMDG: no

IATA: no

14.6 Special precautions for user

no data available

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

no data available

15.Regulatory information

15.1 Safety, health and environmental regulations specific for the product in question

Chemical name	Common names and synonyms	CAS number	EC number
Geranyl linalool	Geranyl linalool	1113-21-9	none
European Inventory of Existing Commercial Chemical Substances (EINECS)			Listed.
EC Inventory			Listed.
United States Toxic Substances Control Act (TSCA) Inventory			Listed.
China Catalog of Hazardous chemicals 2015			Not Listed.
New Zealand Inventory of Chemicals (NZIoC)			Listed.
Philippines Inventory of Chemicals and Chemical Substances (PICCS)			Listed.
Vietnam National Chemical Inventory			Not Listed.
Chinese Chemical Inventory of Existing Chemical Substances (China IECSC)			Listed.

16.Other information

Information on revision

Creation Date	Aug 16, 2017
Revision Date	Aug 16, 2017

Abbreviations and acronyms

CAS: Chemical Abstracts Service
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
IMDG: International Maritime Dangerous Goods
IATA: International Air Transportation Association
TWA: Time Weighted Average
STEL: Short term exposure limit
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
EC50: Effective Concentration 50%

References

IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
ECHA - European Chemicals Agency, website: https://echa.europa.eu/